n-Propanol: flash point and explosive limits

Key values

Source: GESTIS substance database (IFA, October 2026). GESTIS gives the gas group as borderline IIA-B (MESG 0.87 mm); IIB is used here as the conservative choice.

Explosive range and ppm values

n-Propanol can ignite when mixed with air between 2.1 % and 19.2 % by volume. Below the LEL the mixture is too lean to ignite, above the UEL too rich. A rich mixture re-enters the range when it is diluted with air, so concentrations above the upper limit are not safe either.

The lower explosive limit in ppm and g/m³. Useful to compare a gas detector's %LEL reading with ppm values in a measurement report.

Convert another concentration in the LEL calculator

Lighter or heavier than air?

n-Propanol vapour is heavier than air: relative density 2.08 (air = 1). A release sinks and can collect in pits, trenches, drains and basements and travel a long way along the ground.

Flash point and liquid category

The flash point of n-propanol is 22 °C, the boiling point 97 °C.

With a flash point below 23 °C and boiling point above 35 °C, it is a Category 2 flammable liquid under the CLP Regulation: H225 “Highly flammable liquid and vapour”, signal word “Danger”.

At room temperature (20 °C) no ignitable vapour concentration forms above the liquid. An explosive atmosphere can form when the liquid warms up to its flash point, for example in a hot process, a heated vessel or hot weather, or when it is sprayed under pressure (mist). A mist can ignite even below the flash point.

For another liquid, use the flammable liquid category calculator. The product label and safety data sheet apply; mixtures have different values.

Ex equipment selection

Autoignition temperature 385 °C. The maximum surface temperature of equipment in the zone must stay below it: T2, T3, T4, T5 and T6 are suitable; T1 is not, because the limit is not below the autoignition temperature.

Gas group IIB: equipment marked IIB or IIC may be used. The equipment protection level (EPL: Ga, Gb, Gc) depends on the zone, not on the substance; the zone is decided in the explosion protection document from the release and the ventilation. Specific conditions in the certificate (X) and the ambient temperature range are checked separately.

Check an Ex label against n-propanol

Where is it found?

Used as an ink solvent in packaging printing (flexo and gravure), in disinfectants and in coatings.

Where these values sit in the explosion protection document

• Substance properties. The first step of the document is to record these values, with their source, for every flammable substance on site.
• Hazardous area classification. The lower explosive limit and the density are inputs to the release calculation and to the direction in which the zone extends.
• Equipment selection. The temperature class and the gas group decide whether Ex equipment in the zone is suitable.

This page does not decide zones. The type and extent of a zone are calculated from where, how often and how much is released, and from the ventilation.

Sources

Explosive limits, autoignition temperature, gas group, flash and boiling point: GESTIS substance database (IFA, October 2026). GESTIS gives the gas group as borderline IIA-B (MESG 0.87 mm); IIB is used here as the conservative choice.

The relative density is calculated from the molar mass (M / 28.96). The ppm and g/m³ values apply at 20 °C and 1 atm (molar volume 24.055 L/mol). The temperature class follows the rule that the surface temperature must stay below the autoignition temperature.

Molecule model: Wikimedia Commons, Propan-1-ol-3D-balls.png (public domain).

This page is for information. For the substance on your site, the current safety data sheet (section 9) and the relevant standards apply. All substances are in the explosive limits table.

Frequently asked questions

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